The descriptions, locations, ecology and geography data are provided for the 3 new for Ukraine — Petractis hypoleuca (Ach.) Vězda, Placynthium lismorense (Nyl. ex Crombie) Vainio, Verrucaria funckii (Sprengel) Zahlbr. and 20 new for Ukrainian Carpathian lichen species – Absconditella delutula (Nyl.) Coppins & Kilias, Arthonia calcicola Nyl., Aspicilia moenium (Vainio) Thor & Timdal, Bagliettoa baldensis (A. Massal.) Vězda, Bacidia fuscoviridis (Anzi) Lettau, Caloplaca cirrochroa (Ach.) Th. Fr., C. crenulatella (Nyl.) H. Olivier, C. lithophila H. Magn., C. dalmatica (A. Massal.) Zahlbr., C. variabilis (Pers.) Müll. Arg., Fuscidea lygaea (Ach.) V. Wirth & Vězda, Gyalecta subclausa Anzi, Lepraria nivalis J.R. Laundon, Lichenothelia convexa Hensen, Opegrapha rupestris Pers., Protoblastenia calva (Dicks.) Zahlbr., Rhizocarpon lecanorinum Anders, Rinodina tunicata H. Mayrhofer & Poelt, Synalissa symphorea (Ach.) Nyl. and Verrucaria pinguicula A. Massal., which were collected on the rock outcrops of the Ugolsky massive of the Carpathian Biosphere Reserve. Keywords: lichens, Ugolsky massive, Carpathian Biosphere Reserve. [in Ukrainian with Russian and English abstracts]